b) lower c) A white solid producing a brown gas and leaving a white solid. Exactly the same arguments apply to the nitrates. Cation of greater polarizing power distort the carbonate ion more easily and easily decompose it than the cation of lower polarizing power. All these carbonates decompose on heating to give CO 2 and metal oxide. A smaller 2+ ion has more charge packed into a smaller volume than a larger 2+ ion (greater charge density).. Let's have a few examples. You can see that the reactions become more endothermic as you go down the Group. The carbonates become more stable to heat as you go down the Group. I cannot wrap my head around this. Ionisation. Group 2 Oxides & Hydroxides w/ Water & Dilute Acid (6:58) Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Thermal decomposition is the breakdown of a compound into two or more different substances using heat; Thermal decomposition of carbonates. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. The thermal stability increases with increasing cationic size. Going down group II, the ionic radii of cations increases. Thanks for viewing. A smaller 2+ ion has more charge packed into a smaller volume than a larger 2+ ion (greater charge density).. For example, Li2CO3 +heat -> Li ­2 O +CO2 MgCO3 +Heat -> MgO +CO2 Na2CO3 +heat -> no effect. Nitrates of both group 1 and group 2 metals are soluble in water. The Effect of Heat on the Group 2 Carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Source(s): https://shrinke.im/a8pDM. Top Answer. About this resource. All these carbonates decompose on heating to give CO2 and metal oxide. Hey guys, I had a question on why thermal stability increases down Group 2? Does sodium nitrate decompose when heated? All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Solubility. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding Let's use MgCO 3 as an example. Thermal Decomposition Temperatures for Carbonates, Nitrates and Hydroxides. Ionisation. Thermal Stability is the decomposition of a compound on heating. This page offers two different ways of looking at the problem. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. As we go down the group, the carbonates have to be heated more strongly before they will decompose. 2012-08-13 15:58:41. It consists of a carbon atom surrounded by three oxygen atom in a trigonal planar arrangement. Info. (ii) Carbonates. Stability of metal carbonates One common reaction of any metal carbonates is known as thermal decomposition. The increasing thermal stability of Group 2 metal salts is consistently seen. Why na2co3 does not decompose on heating? The FactsThe effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO3 < MgCO3 < CaCO3 < SrCO3 < BaCO3. This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. If "X" represents any one of the elements: As you go down the Group, the carbonates have to be heated more strongly before they will decompose What is the correct condensed formula for 2 2 4 Trimethylpentane? 1. Best answer. Analysis. Whereas bicarbonates give carbonate, water and carbon dioxide. 2. Thermal stability. People also ask, why does thermal decomposition decrease down Group 2? It describes and explains how the thermal stability of the compounds changes as you go down the Group. As we go down the group, the carbonates have to be heated more strongly before they will decompose. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. The nitrates also become more stable to heat as you go down the Group. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. The next diagram shows the delocalised electrons. You should look at your syllabus, and past exam papers -. I am a metal and placed above iron in the activity series. The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3. Created: Jan 12, 2018. doc, 32 KB. Thermal decomposition is the term given to splitting up a compound by heating it. The oxide ion is relatively small for a negative ion (0.140 nm), whereas the carbonate ion is large (no figure available). The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Created: Jan 12, 2018. doc, 32 KB. The larger compounds further down require more heat than the lighter compounds in order to decompose. It means the stability increases from M g C O 3 to B a C O 3 . Whereas bicarbonates give carbonate, water and carbon dioxide. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . Thermal stability increases down the group because the size of the cation (positive ion) increases, so the lattice energy of the carbonate decreases, but the lattice energy of the oxide decreases faster. Using the above evidence place the metal carbonates in order of thermal stability. Here's the decomposition reaction for Group 2 metal carbonates and the temperatures that the salts decompose. Decomposition becomes more difficult and thermal stability increases. When metal carbonates are heated, they break down to … The thermal stability of Group II carbonates increases as we descend the group. How many variables are there in the factorial research design of 2 * 3 * 2? It also identifies and explains the trend in the solubility and thermal stability of group 2 metal compounds. It describes and explains how the thermal stability of the compounds changes as you go down the Group. When a smaller 2+ ion comes near a carbonate or nitrate ion, … Hence, their polarising power also decreases. 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